Evaluation of calcium carbide residue and fly ash as sustainable binders for environmentally friendly loess soil stabilization

The incorporation of waste materials into cementitious binders serves as a strategy to diminish waste volume and lower carbon emissions. This study presents an in-depth evaluation of calcium carbide residue and coal fly ash as alternative binders. The assessment of raw materials emphasized their chemical composition and potential for pozzolanic reactions. Based on these factors, the optimal ratio of Ca/(SiO2 + Al2O3) in the raw materials was determined to be 1.5. Therefore, this study was designed to vary the raw material composition with a CaO/(SiO2 + Al2O3) ratio ranging from 1.7 to 0.9. Upon investigating the effect of the raw material proportion on the compressive strength of pastes and mortars, the composition yielding the highest compressive strength was selected for its potential application as a stabilizer for loess soil. A mixture of calcium carbide residue and coal fly ash with a Ca/(SiO2 + Al2O3) ratio of 1.5 resulted in the highest compressive strength at long curing periods in both pastes and mortars. Mineralogical and microstructural analyses revealed several products, beyond those formed from the pozzolanic reactions, that occurred and enhanced the compressive strength of samples. The highest performing mixture of carbide residue and coal fly ash was then used to stabilize loess soil at 10–25 wt%. The unconfined compressive strength, along with mass and strength loss due to wetting and drying cycles, was also studied. It was observed that the unconfined compressive strength of the stabilized soils remained consistent after six wet-dry cycles but decreased after twelve cycles due to microcracks. The findings suggest that carefully designed mixtures based on the chemical interactions of calcium carbide residue and coal fly ash can offer a sustainable, efficient approach for soil stabilization, potentially revolutionizing construction practices.

In the quest for sustainable construction, the industry is actively seeking supplementary cementing materials (SCMs) as alternatives to Ordinary Portland Cement (OPC).The reasons are threefold: environmental impact, resource conservation, and cost-effectiveness.OPC production contributes about 8% of the world's CO 2 emissions, hence a more environmentally friendly option is required.SCMs reduce waste and conserve non-renewable resources because they are made from industrial byproducts including fly ash, slag, and silica fume.Moreover, SCMs enhance concrete durability, lower maintenance costs, and reduce overall project expenses, making them a viable, eco-friendly alternative for the future of construction.Over the past few years, the concrete sector has undertaken several measures to minimize its carbon footprint.These measures include reducing the consumption of raw materials, improving energy efficiency in kilns, transitioning from fossil fuels to renewable sources, and incorporating supplementary cementitious materials, also known as pozzolanic materials, such as coal fly ash (FA), ground granulated blast furnace slag (GGBFS), rice husk ash (RHA), circulating fluidized bed combustion fly ash (CFA), and locally sourced materials.The pozzolanic materials can undergo a reaction with calcium hydroxide during cement hydration, leading to the generation of extra calcium silicate hydrates (C-S-H).As a

Materials
In this investigation, fly ash (FA) and calcium carbide residue (CCR) were both used as binder ingredients.The CCR waste is a by-product obtained during the acetylene gas manufacturing process in Samut Sakhon province, Thailand.To prepare the CCR, it underwent a drying process at 105 °C for 24 h in an oven, then grinding into a fine powder and sieving using a 0.075 mm sieve 2 .The chemical composition of the raw materials used in this work was determined through the Energy-dispersive X-ray fluorescence (EDXRF) technique, and the test results suggest that the main chemical component of CCR is calcium oxide, as indicated in Table 1.The CCR presented a specific gravity of 2.56 and a specific surface area of 218.80 m 2 /kg. Figure 1 (a) presents the Thermogravimetric-Differential Thermal Analysis (TGA-DTA) curves of CCR, indicating the weight loss of the samples with increasing temperature.The first derivative of the TGA-DTG curves was also analyzed to better understand the thermal response of the materials.Two main stages of weight loss were observed: the first stage occurred from 375 °C to 495 °C, likely due to the decomposition of Ca(OH) 2 in CCR powders 26 , while the second stage occurred www.nature.com/scientificreports/ between 625 °C and 775 °C and was attributed to the decarbonation of calcite 27 .The phase content of CCR was determined through analysis of X-ray diffraction patterns using the Rietveld refinement technique, as illustrated in Fig. 1b and detailed in Table 2.The predominant peaks of calcite (CaCO 3 ) and portlandite (Ca(OH) 2 ) were observed, with the phase content suggesting that CCR consists of 66 wt% calcite and 32 wt% portlandite.The SEM image of CCR exhibited irregular shapes and heterogeneous morphology, as shown in the inset figure of Fig. 1b.This is characterized by a mixture of large and small particles, indicative of a broad size distribution.The particles possess a rough, uneven surface, with some exhibiting angular shapes and others appearing more rounded.
The used fly ash is obtained from lignite fly ash at the Mae Moh power plant located in Lampang province, Thailand.According to ASTM C618 standards, the chemical analysis of the fly ash was performed 28 , and the results are summarized in Table 1.The chemical analysis revealed that the sum of SiO 2 , Al 2 O 3 , and Fe 2 O 3 accounted for 66.15% of the total composition, which categorizes this fly ash as class C.Moreover, the sulfur trioxide (SO 3 ) content is determined to be 4.08 wt%, which is marginally below the maximum threshold prescribed by ASTM C618 standard.This standard recommends that the SO 3 content should not surpass 5.0 wt% for class C fly ash.It should be noted that the SO 3 present in the FA might undergo a chemical reaction with calcium hydroxide in the CCR.This interaction is believed to instigate a deleterious effect, potentially leading to the development of cracks and subsequent expansion in the composition of pastes, mortars, and other stabilized materials 29 .
Based on the XRD patterns shown in Fig. 2, the primary crystalline minerals identified in FA are quartz, anhydrite, ferric oxide, and lime.Additionally, amorphous phases were observed, indicated by the dispersion peaks between 15° and 30°.The Rietveld refinement results investigated that FA contains 57.16 wt% amorphous    www.nature.com/scientificreports/phases, which might indicate high pozzolanic activity 30 .The morphology of the FA particles was determined with a scanning electron microscope (SEM), and the results are presented in Fig. 2b.The SEM micrograph revealed that all the FA particles had a spherical shape, with a broad range of particle sizes ranging from the nanoscale to larger than 10 microns.The present study utilized natural loess soil obtained from Khon Kaen University, Thailand.The grain size distribution and consistency test results revealed that this soil is classified as silty sand corresponding to the USCS classification system.The soil was sieved through a 2 mm sieve before being used.
The XRD patterns of loess soil are shown in Fig. 3a.The predominant component of the loess soil is quartz.This  Amorphous     3b displays an SEM photo of the original loess, which clearly illustrates the shape of the soil particles.The image indicates that the loess soil is composed of several small particles with a spherical shape that join together with weak agglomeration to form larger particles.

Mixture design and sample preparation for paste and mortar
To determine the optimal mixing ratio of CCR to FA, the chemical composition of the raw materials was considered, which is highly influential on the rate of pozzolanic reaction in the mixture.The optimal molar ratio of CaO/(SiO 2 + Al 2 O 3 ) for the pozzolanic reaction between amorphous siliceous or aluminous materials and calcium hydroxide in the presence of water were also study referred to Eqs. ( 1) and (2) 31,32 .These equations suggest that the theoretical ratio of CaO/(SiO 2 + Al 2 O 3 ) required to complete the pozzolanic reaction is 1.5.Subsequently, we utilized the content of CaO, SiO 2 , and Al 2 O 3 in the raw materials to derive an empirical formula for the optimized CCR:FA ratio, which we computed to be 0.81.However, several investigations have suggested that the pozzolanic reactions between Ca(OH) 2 with SiO 2 and Al 2 O 3 are very complicated [33][34][35][36][37][38] .Therefore, this investigation designed the raw material ingredient with a CaO/(SiO 2 + Al 2 O 3 ) ratio in the range of 1.7 to 0.9.The specific mixture proportions for the pastes can be found in Table 3.
One aspect of significance in this study is the estimation of the optimal CCR to FA mixing ratio, which was predicated on the chemical composition of the materials together with the characteristics of pozzolanic reactions.However, it is pertinent to acknowledge that the pozzolanic reactions, as shown in Eqs. ( 1) and ( 2), depend on the amorphous SiO 2 and Al 2 O 3 from FA, amounting to merely 57.16 wt%.This indicates that not all SiO 2 or Al 2 O 3 are involved in the reactions.In a similar vein, only a fraction of CaO from CCR, specifically the portlandite phase constituting 32.02 wt%, undergoes reaction.Therefore, an approach that determines the optimal mixing ratio from the amorphous phase content in FA and the portlandite phase content in CCR may offer a more reasoned basis and should be contemplated for estimating the optimal mix.Nonetheless, the analysis of the amorphous phase content in raw materials through the Rietveld refinement technique, derived from X-ray diffraction patterns, presents a considerably complex process.This method necessitates specialized expertise, sophisticated tools, and advanced techniques.Considering these considerations, the present study elected to establish the optimal ratio of raw materials based on their chemical composition to facilitate user convenience.The optimal CCR to FA mixing ratio, calculated with a focus on the reactive phases, the amorphous phase in FA and portlandite in CCR, was ascertained based on the siliceous pozzolanic reaction (Eq.( 1)).The calculation result revealed that the optimal CCR/FA ratio is 3.30.This ratio stands in contrast to the experimental design implemented in this research, as detailed in Table 3.This divergence is a point of considerable interest and necessitates extensive investigation into future work.
The CCR and FA dry ingredients were mixed using the ball-milling method at low speed for 5 min until a well-mixed powder was obtained.The raw materials were then transferred to a mixer, and the paste was mixed following the ASTM C 305-20 standard 39 .The water-to-binder ratio was fixed at 0.65 for all compositions.The fresh pastes were cast into 25-mm cube molds and kept at room temperature of 25 ± 1 °C with relative humidity > 95%) for 24 h before being removed from the molds.The demolded samples were then placed in a curing room with a relative humidity exceeding 60% until achievement of designated test age.
The specific mixture proportions for the mortar samples can be found in Table 4.The ratio of CCR/FA is fixed in a manner similar to the paste mixture design.Each specimen was prepared with a constant water-to-binder ratio (w/b) of 0.58 and a sand-to-binder ratio of 2.75.
It should be noted that the w/b used in this study is slightly higher than the recommended ratio of 0.485, as per ASTM C109 standard 40 .This is due to the fact that, although the river sand used in this work is natural silica sand conforming to the requirements of the graded standard sand in ASTM C778 standard 41 , it exhibits higher water absorption and a more angular shape compared to Ottawa sand, resulting in a higher water demand.However, it should be acknowledged that an excess of water added at any time will result in free water being trapped in the concrete or rising to the top, causing bleeding.To achieve the desired workability, a type F superplasticizer was introduced to ensure a flowable consistency within the range of 110 ± 5%.Mortar mixtures were produced as 50 mm cubes in accordance with the specifications of the ASTM C305-20 standard.The OPC mortar was created and designated as the control mixture to evaluate the mechanical properties of CCR-FA binders. (1)

Mechanical properties
The compressive strength of the CCR-FA binders was measured at curing ages of 7, 14, 28, 56, and 91 days.For each age, three 25 mm cubes of paste and three 500 mm cubes of mortar were selected and tested using a compressive testing machine.The testing procedure was carried out according to the ASTM C109 standards 40 .The applied load speed was controlled at 50 N/s and 900 N/s for paste and mortar, respectively.

Phase formation and microstructure characterization
In support of the mechanical property evaluation, phase formation and microstructural investigations were conducted via the X-ray diffraction (XRD) method and scanning electron microscopy (SEM), respectively.X-ray powder diffraction patterns were obtained using Cu-Kα radiation (λ = 1.5406Å) radiation on a D Bruker, D2 PHASER.The diffraction pattern (2θ) was scanned over 5°-70°, with a step size of 0.02 and a time per step of 0.5 s.For SEM analysis, a field emission scanning electron microscope (Thermofisher, Aspero S) equipped with energy-dispersive X-ray spectroscopy (EDS) is operated at a working distance of approximately 10 mm and an accelerating voltage of 5.0-10 kV.For the SEM-based microstructural analysis, the hardened pastes were initially reduced to particles within a size range of 2-5 mm.Subsequently, immersion in acetone for a duration of 24 h was employed to ensure the removal of any residual free water, following the methodology outlined by Uzal et al. 42 .Thereafter, the samples underwent a meticulous vacuum drying process at 60 °C for 24 h, to prepare them adequately for subsequent testing procedures.

Sample preparation and testing program for soil stabilization
The CCR-FA mixture with the optimal CaO/(SiO 2 + Al 2 O 3 ) composition, which exhibited the highest mechanical performance for both paste and mortar, was chosen as the binder to improve the engineering properties of the loess soil.The mixture of CCR-SF, which provided the highest binding performance from paste and mortar test results, was employed as a stabilizer for 10-25 wt% of the dry soil.The stabilizer, dry soil, and water at optimum water content were well mixed for 10 min by the milling machine (Table 5).After mixing, the fresh mixture was weighed and placed in PVC cylinder molds with a diameter of 50 mm and a height of 100 mm and compacted on a vibrating table for 45 min with a density in the range of 95% to 105% of the maximum dry density.The molded samples were covered with plastic sheets to retain moisture and left to cure at room temperature.After a curing period of 72 h, the samples were taken out of the molds and then sealed with plastic sheets until the required curing times for testing.The unconfined compressive strength (UCS) test was carried out using a compression machine with a vertical deformation rate of 1.0 mm per minute.To ensure the reliability of the results, three samples of each mixture were prepared and tested under identical conditions at curing ages of 7, 14, 28, and 56 days.The preparation processes of the samples and the testing for UCS are illustrated in Fig. 4a.Loess soil is highly vulnerable to changes in moisture content, which can significantly impact its strength and deformation behavior.As such, this study aimed to investigate the mass and strength loss resulting from wetting and drying cycles.The method for determining mass loss due to wetting and drying conditions, along with strength loss, was adopted from the ASTM D559 standard 43 .Three samples were cured for a specified curing period, and their original masses were recorded.The samples were then immersed in room-temperature water for 5 h.Following this soaking period, the samples were removed, and their masses were recorded.The samples were then moved to an oven and heated at 70 °C for 42 h before being weighed again.This entire process constituted one cycle of the wetting and drying test, and the testing continued until the completion of the twelfth www.nature.com/scientificreports/cycle.To accurately assess the performance of stabilizers in conditions specific to Thailand, a tropical country with frequent rainfall throughout most of the year, a carefully considered curing period is essential.The curing period before exposure to a wet-dry cycle environment should extend beyond 28 days.This duration is necessary to allow adequate reaction time for the stabilizer to achieve its intended effect.However, this period should not exceed 60 days, aligning with the typical dry spell duration in Thailand.This recommendation is in accordance with the comments provided by the Department of Highways (DOH), Thailand.Hence, the testing was conducted on samples that had been cured for 28 days and 56 days.The UCS test on the samples subjected to wetting and drying processes was performed at the end of the first, sixth, and twelfth cycles.The testing program for mass loss and strength loss of stabilized soils under wetting and drying processes is detailed in Fig. 4b.

Compressive strength of past and mortar
In Fig. 5, the development of compressive strength in CCR-FA pastes is presented for several curing ages.At 7 days of curing, the compressive strength of pastes ranged from 1-2 MPa, except for the C-0.9 mixture, which showed a compressive strength lower than 0.5 MPa.The compressive strength of all mixture compositions tended to increase continuously with an increase in curing age.The C-1.5 mixture displayed the highest compressive strength at a long curing period, with a strength value of 7.89 MPa at 91 days of curing.However, the strength  www.nature.com/scientificreports/development of CCR-FA binders over time showed an abnormal trend for some mixture compositions, as the compressive strength may either increase or decrease with an increase in curing period.The compressive strength characteristics of the CCR-FA binder were investigated for mortar samples using OPC as the reference binder, as illustrated in Fig. 6.The results indicate that the compressive strength increases with an increase in curing age for all mixtures.To compare the compressive strength of CCR-FA mortar with that of OPC, the relative compressive strength was calculated and plotted in Fig. 7.At the 7-day curing age, the compressive strength of CCR-FA mortar exhibited a notable reduction compared to that of OPC mortar, with a relative compressive strength of less than 20% for all mixtures.This indicates that the pozzolanic reactions occurring in the CCR-FA binder generate reaction products slowly, which gradually increase over time.After 91 days, the relative compressive strength of CCR-FA binders improved to higher than 60% for all mixtures.The highest relative compressive strength of 68% compared to OPC mortar was observed in the C-1.5 mixture, which corresponds with the compressive strength test results for paste.These findings suggest that CCR-FA binder can be a viable alternative to OPC binder in mortar, particularly for long-term applications where strength development over time is crucial.

Microstructural analysis
The TGA-DTA facilitates a preliminary identification of the reaction mechanisms in the CCR-FA paste.Figure 8 presents the TGA-DTG curves of the CCR-FA paste after a curing period of 56 days.At temperatures below 120 °C, the weight loss observed is primarily due to the evaporation of free water from the sample.Beyond this temperature threshold, the results reveal three major stages of weight loss.The first stage involves the dihydroxylation of hydrated components in CHS gels, ettringite, and AFm phases, which occurs between 150 °C and 400 °C.The second stage, evident between 420 °C and 500 °C, corresponds to the dehydration of Ca(OH) 2 .
The final stage, occurring between 550 °C and 800 °C, is marked by the decomposition of calcite (CaCO 3 ) in the raw materials, resulting in the formation of CaO and CO 2 .These test results provide insights into the potential phases identifiable in the hydrated pastes.
The mineralogical analysis of hydrated pastes, formulated from CCR and FA mixtures with varying CaO/ (SiO 2 + Al 2 O 3 ) ratios, was conducted at different curing ages using the X-ray diffraction (XRD) method (Fig. 9).The results revealed that the diffraction peak characteristics exhibited slight variations due to differences in the mixture proportions.One notable observation from the XRD patterns was the presence of calcite, which  As the curing age increased, a significant enhancement in the peak intensity of these hydration products was observed.This effect was particularly evident in samples with lower CaO/(SiO 2 + Al 2 O 3 ) ratios.The intensity peaks of ettringite, relative to calcite, were higher in samples with low CaO/(SiO 2 + Al 2 O 3 ) mixtures compared to those with high CaO/(SiO 2 + Al 2 O 3 ) ratios.This outcome can be attributed to the higher content of fly ash in the low CaO/(SiO 2 + Al 2 O 3 ) samples, which serves as the raw material responsible for generating the ettringite phase.
The results of SEM-EDS analysis on CCR-FA pastes with different CaO(SiO 2 + Al 2 O 3 ) ratios and curing periods are presented in Figs. 10 and 11, respectively.The primary cementing agent in the hydration products, Calcium Silicate Hydrate (CSH), was identified by its Ca/Si atomic ratio obtained from EDS analysis.However, several previous studies examining the nanoscale structure of C-S-H suggest that there are various CSH structures, with defective SiO 4 tetrahedra chains resulting in a broad Ca/Si ratio ranging from 0.83 to 2.25 44 .Therefore, the identification of CSH using the SEM-EDS technique is only a rough estimation due to the highly complex and potentially defective structure of CSH.The hydration products of C-1.7 and C-1.5 pastes, which had a high content of CCR powder, consisted mainly of plate-like portlandite after 28 days of curing.Nonetheless, extending the curing duration to 91 days led to a reduction in portlandite crystals, which were replaced by CSH and CaCO 3 due to the pozzolanic and carbonization reactions.For the C-1.3, C-1.1, and C-0.9 pastes, which had a rich content of fly ash in their raw materials, unreacted fly ash was clearly observed.Several types of hydration products were observed, with CSH being the primary cementing agent formed from the hydration reactions of the raw materials, alongside ettringite, which is present but does not contribute to cementing ability.These results were consistent with the XRD investigation results.The microstructural investigation results suggest that the use of CCR and fly ash as raw materials can lead to the formation of various types of hydration products, which can enhance the strength and durability of the resulting reaction products.

Soil stabilization
Figure 12 illustrates the variation in the UCS of loess soil stabilized with a CCR-FA, at a CCR -FA ratio of 0.69, across various curing periods and stabilizer contents.The UCS of the stabilized soils increased in a nonlinear manner with the duration of the curing periods.In the absence of the stabilizer, the UCS of the loess remained at 595 kPa.However, with the addition of a 10 wt% CCR-FA stabilizer, the UCS reached 3751, 4289, 6441, and 6848 kPa after curing periods of 7, 14, 28, and 56 days, respectively.These values were approximately 6, 7, 11, and 12 times higher than those of the unstabilized soil, demonstrating a remarkable improvement.The influence of the curing duration on the strength of the stabilized loess soils was found to be dependent on the quantity of stabilizer added.A slight improvement in strength was observed during the 7-days to 14-days curing period when a low stabilizer content was used, while a significant increase was observed between the 14-days to 28-days curing period.Notably, when the stabilizer content was increased to 25 wt%, a substantial enhancement in strength was observed between the 14-days and 28-days curing periods.Furthermore, a significant improvement in the UCS of the stabilized loess was observed for longer curing periods, specifically from 28 to 56 days, with an increase in the stabilizer content.These results suggest that a higher content of CCR-FA stabilizer is more effective for longer curing periods due to the prolonged pozzolanic reaction required for the generation of the cementitious binder.
The results of the wet-dry durability tests, represented by mass losses after each cycle, were graphed against the curing durations for all stabilized soil combinations.These results are displayed in Figs. 13 and 14.It was found that samples stabilized with a CCR-FA mixture stabilizer significantly maintained their original weight and survived a full 12 cycles of wet-dry testing.In the case of a 10 wt% stabilizer addition, the mass of samples gradually decreased with each wetting and drying cycle, but the samples still retained more than 90 wt% of their www.nature.com/scientificreports/original mass after 12 cycles (refer to Table 6).The study found that increasing the content of CCR-FA stabilizer by 15-25 wt% led to an improvement in the rate of leaching from wetting and drying cycles.This improvement can be attributed to the larger content of cementitious agents resulting from the pozzolanic reaction of the stabilizer.The results, as shown in Fig. 13, indicate that samples subjected to a longer curing period of 56 days demonstrated superior performance and survived a full 12 cycles of wet-dry testing.Figure 15 illustrates the evolution of UCS with the number of wet-dry cycles for samples tested in this study.The UCS initially increased with the number of wet-dry cycles up to 6, compared to their residual strength.www.nature.com/scientificreports/However, the UCS begins to decrease when the number of wetting and drying cycles reaches 12.The impact of wet-dry cycles on UCS development in stabilized soils was observed to be similar in several previous studies, where UCS increased initially with the number of cycles and then gradually decreased as the cycles continued [45][46][47] .These previous studies suggested increasing the curing temperature during the drying phase of stabilized materials can accelerated the reaction rate of stabilizers and enhance the strength of the mixtures.The relative UCS demonstrates a significantly higher increase in compressive strength for soils stabilized and cured for 28 days, compared to those cured for 56 days, before the wet-dry cycles test (Fig. 16).This can be attributed to the fact that the original UCS of the soils stabilized and cured for 56 days is significantly higher than that of the samples cured for 28 days, due to the longer curing period.The decrease in UCS after longer wet-dry cycles is attributed to the repeated drying-wetting process, which induces microcracks and compromises the integrity of the specimen 48 .This allows water to infiltrate along the cracks, leading to a reduction in UCS.Moreover, samples cured for 56 days exhibit a smaller decrease in strength due to prolonged wet-dry cycles compared to samples cured for 28 days (Fig. 16).This suggests that a longer curing period, which generates more cementing materials, helps to improve the durability of stabilized soils under a wet-dry cycle environment.From a mechanical perspective, the shear strength of soils is composed of two primary components: cohesion and the internal friction angle.Previous studied have demonstrated that during dry-wet cycles, water predominantly disrupts the bonds between  www.nature.com/scientificreports/soil particles, leading to a reduction in cohesion.However, the process of dry-wet cycling has minimal impact on the roughness of soil particles, and as a result, the internal friction angle remains relatively unchanged 47,49 .However, the significantly reduction in UCS of stabilized soil with high stabilizer content of 25 wt% (S25) cured for 56 days after 12 cycles of wet-dry testing is doubtful.This may be high cementing agent generated from stabilizer loss their bonding ability after longer cycle of wet-dry environment and resulting in significantly reduction in cohesion.However, deep investigation on this point need to more clarify.The notable decrease in the UCS of the stabilized soil sample with a high stabilizer content of 25 wt% (S25), cured for 56 days following 12 cycles of wet-dry testing, raises questions.This reduction may be attributed to the high concentration of cementing agents from the stabilizer losing their bonding effectiveness after prolonged exposure to wet-dry cycles, leading to a significant decrease in cohesion.However, this hypothesis needs further detailed investigation to elucidate the underlying mechanisms and confirm the observed trend.

Conclusion
This study explores the development of calcium carbide residue (CCR) and fly ash (FA) as alternative binders, proposing them as sustainable options alongside ordinary Portland cement for loess soil stabilization.X-ray diffraction analysis indicates that raw FA contains 57 wt% of amorphous phase content, while CCR consists of 66 wt% calcite and 32 wt% portlandite.The CCR-FA mixture with a Ca/(SiO 2 + Al 2 O 3 ) ratio of 1.5 yielded the highest compressive strength over extended curing periods.However, further investigation is needed to optimize the mixture proportions and understand their long-term behavior under various environmental conditions.The application of the CCR-FA mixture in soil stabilization, particularly with a Ca/(SiO 2 + Al 2 O 3 ) ratio of 1.5, demonstrated significant improvements in unconfined compressive strength.The soils stabilized with the CCR-FA binder exhibited an initial enhancement in unconfined compressive strength, observable through up to six

Figure 4 .
Figure 4. (a) Preparation processes for stabilized soils and the testing for UCS and (b) Testing program for mass loss and strength loss of stabilized soils under wetting and drying processes.

Figure 5 .
Figure 5. Age-dependent compressive strength development of paste.

Figure 9 .
Figure 9. XRD Patterns of CCR-FA pastes with different compositions.

Figure 12 .
Figure 12.The correlation between the UCS and the fraction of stabilizer under different curing ages.

Figure 13 .Figure 14 .
Figure 13.Variation in mass resulting from wet-dry cycles of stabilized soil with cured at 28 days before testing.

Figure 15 .
Figure 15.The UCS stabilized soil after wetting and drying processes.

Figure 16 .
Figure 16.Relative compressive strength of stabilized soil after wetting and drying processes.

.
Chemical composition and physical properties of raw materials.

Table 2 .
Quantitative phase analysis of raw materials derived from X-ray Diffraction patterns using the Rietveld refinement method.

Table 3 .
Mixture design for pastes with different CCR/FA ratios.

Table 4 .
Details of mortar mix compositions.

Table 5 .
Mixture proportions for soil stabilization.

Table 6 .
Residue mass percentage of stabilized soil after wetting and drying cycle.